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Reproduced
with kind permission of Barbara Bird - Professional Groomer & Writer

The Essence of White
It is important to realize that white is not a color in
itself, but the absence of color. White hair occurs when no melanin is
formed in the papilla, and thus no color pigment is present in the
cortex of the hair. White hair is actually translucent. Light passes
through the hair shaft. This point was slammed home to me at the hair
show when I sat down at a booth that had a magnifying scalp scanner and
a video monitor, ostensibly so one could determine if one’s hair was
thinning. At about 100X, a human scalp is a bit gross, but I was curious
as to what I could see on my head. When the technician moved the scanner
to my white forelock of not-colored hair, I saw through the hair shafts
to the very center. Yes, folks, I saw my own MEDULLA! On the very
outside of the hair shaft was a dim outline that I assume was the hair
cuticle, and then a thicker area of nothing that was the cortex, and in
the very center a fine line that was the medulla. The rest of my hair
shafts were varying shades of red, where the red dye had been deposited
on the shaft of the hair cortex. You could see where some individual
hairs had taken the color better than others, but none were transparent
like the white.
The Nature of White Pet Hair
White dog hair tends to be thinner than hair with color
and often has fewer cuticle layers than dark hair. It also can be more
porous. These two qualities magnify the challenge of maintaining white
pets. Because of the more porosity, the white coat holds dirt and
because of the thinner nature of the hair cuticle, staining of the
cortex is more likely to occur.
Ways to Achieve Whiteness
1. Deep Cleaning
Once we understand that white is the absence of
color, then it becomes apparent (optical pun) that cleaning the hair is
the first task of whitening. The more thoroughly a product removes dirt
and deposits from the hair shaft, the more whitening we will accomplish.
The cleaner the hair, the more light can pass through. The cleansing
action of a shampoo for white coat becomes paramount. It is not
surprising, then, that whitener shampoos are often more harsh than many
others. These shampoos are using higher concentrations of the more dirt
lifting surfactants, such as Sodium Lauryl Sulfate. White show dogs are
the most frequently bathed, at least weekly, to quickly remove dirt and
prevent staining. As with your carpets, staining is most likely to occur
when substances are allowed to “set” in the hair. Dookie, the
long-haired Akita pictured above, is bathed 2-3 times a month to keep
his coat at its whitest. Some whitener shampoos may contain surfactants
with bleaching properties that will actually penetrate the hair shaft
and decolorize stains through a process of oxidation. Chemically, an
oxidizing agent is any substance that causes another substance to lose
one or more electrons. This bleaching, or decolonization, is due in part
by the ability of the bleaching substance to remove those electrons that
are activated by visible light to produce various colors. #1 All Systems
White Lightening
Shampoo is a product that has bleaching action.
Such shampoos commonly contain a warning on the label about not allowing
the product to sit on colored hair. Not a good choice for a
parti-colored animal. There are also whitening shampoos that utilize
enzymes to break down dirt and stains into particles that can be
successfully removed by more gentle surfactants. EZ Groom Crystal White
is an example of this type of product. Enzymes work best in higher
temperatures, partly because the hair cuticle is raised by heat so as to
allow the enzymatic action to occur in the cortex, where the stain
resides. Follow such treatment with a cool rinse to calm and close the
hair cuticle. Conditioning is advised.
Products using powerful surfactants and bleaching
agents can dry out the coat and possibly damage the hair cuticle. It is
important to rinse very well and to use restorative conditioners in
conjunction with these products. Damaged coat will return dirtier and
dirtier because the broken cuticle will attract and hold more dirt. A
product that was especially formulated to follow
colour
treatments is Chris Christensen's After Bath.
Rinse, a light conditioner that also removes any
shampoo residue and mildly acidifies, tightening and firming the hair
cuticle.
Some white dogs have coats that are not true white,
but have an “off-white” or cream-colored tinge. This means that there is
some melanin in the hair’s cortex. While you can use products that will
make this coat appear whiter, there is no way of bleaching this hair
pigment without totally damaging the coat. For a temporary measure, this
slightly colored coat can be coated with white powder or chalk.
2. Bluing
“Brightness is measured as a reflectance in the
blue portion of the visible spectrum. Complete reflectance provides a
white
colour.”(www.chem.vt.edu/chem-dept)
There you have it: Whiter whites are achieved by optical illusion!
Traditionally white fabrics and white hair have been treated with bluing
agents so as to deposit a slight amount of blue color to reflect the
“blue portion of the visible spectrum.” Any shampoo that is blue or
violet in color is using this principle. The downside of these products
is that sometimes you can accidentally deposit a little too much blue,
and the eye will see blue or violet instead of blue-white. This can
happen by applying concentrated blue product on dry, porous coat, or
from leaving the product on longer than recommended. Always follow the
instructions, please! The more porous the hair, the more quickly and
deeply it will take the coloring agent.
3. Optical Brighteners
Many contemporary whiteners utilize the reflectance
principle and increase the appearance of whiteness by making the coat
shine and sparkle, literally reflecting more light. Awapuhi, or Hawaiian
White Ginger Root, is a botanical substance that has makes hair shiny
and white hair appear whiter. There are other, less natural, substances
that also create this effect, including silicones. The absolutely
whitest white coat will come from effective cleaning plus some optical
brightener. The original pet whitener shampoos all consisted of strong
detergents plus blue coloring. Some of the most contemporary products
are formulated with bleaching surfactants or enzymatic cleaners and
ingredients that maximize shine and light reflection. Either way, you
will get a whiter coat. Conditioners containing silicones not only leave
a coat shiny and bright, but also protect the hair shaft from collecting
dirt. Some silicone products, however, tend to yellow white coat if they
are allowed to build up. Whoops! To prevent build-up problems, use
quality products and occasionally treat with a clarifying shampoo to
remove old product.
What is Staining?
Putting myself on the spot, so to speak, :-), I am going
to create this definition: Staining occurs when pigmentation from a
substance penetrates the hair cuticle and is deposited within the cortex
of the hair shaft(s). Since the detergent surfactant in a shampoo works
on the surface of the hair cuticle, the stain is not removed by
shampooing. The hair has in fact been dyed. Urine, coal tar from
pavement, ground in grasses, food coloring, and dyes from toys are among
the substances that can cause staining. The chemistry of some dog’s
saliva can cause staining, especially if they lick themselves. Reddish
brown tear stains are particularly bothersome and permanent.
Dealing with staining is a challenge, often requiring
trying various techniques? Prevention is the most effective approach,
but does not always work. Daily removal of offending substances such as
tears, saliva or urine is recommended. Sometimes changing the diet or
the water can help control staining from saliva or tear stains. It is
helpful to have realistic expectations. Stain removal is rarely
accomplished in a single effort, such as a visit to the groomer.
Bleaching is best done in stages, gradually lifting the offending color
from the hair shaft. Attempting to bleach out stains in one sitting can
result in permanent hair damage. The trick for many pet owners becomes
to lift out staining faster than it is being redeposited.
Secrets from the Dog Show
Those grooming dogs for the show ring have to get serious
about staining that is perceived as a blemish to the presentation of a
show dog. One home-made formula for bleaching stains is equal parts
twenty volume hydrogen peroxide and Milk of Magnesia. To this is added
enough cornstarch to make a paste. Let it dry on the hair and then wash
off and follow with a good conditioner. Beware! The hydrogen peroxide is
an emetic and will make a dog vomit if licked off and ingested. Another
home remedy for staining is to cover the stain with baking soda made
into a paste and let it sit for 15-20 minutes. A variation to this is to
add baking soda to the shampoo. Baking soda has a very alkaline pH which
lifts the hair cuticle and helps to remove dirt that has impeded deep in
the hair, causing staining. Either use of baking soda should be followed
by an acidifying treatment, as simple as a vinegar rinse, to close the
cuticle again and prevent further staining or hair breakage.
A Warning
With few exceptions, almost all whitening products can
cause damage if they get in a dog’s eyes. Harsh detergents, bleaches,
enzymes, dyes, and optical brighteners can hurt the tender tissues of
the eyes. Some of these ingredients actually attack protein. Always
exercise additional care with these products around your pet’s eyes. If
you even think you might have accidentally allowed whitening product of
any kind to get in the eye, flush the eyes with tepid water. Flushing
immediately can save costly veterinary bills. Don’t freak, just flush!
Allergic Reactions
Some white dogs have sensitive skin and/or can be
allergic to some of the ingredients in whitener shampoos. It is
important that the groomer be aware of this possibility and takes it
seriously if a client reports itching or discomfort in a pet that has
been treated with a whitener shampoo. Discontinue use of the offending
product, and if possible re-bathe the pet in a mild, hypoallergenic
shampoo followed by a cool rinse. If a dog has a history of allergy
problems, it is probably best to not risk a reaction with a colorant
product.
Summary
Maintaining white pets requires more aggressive cleaning
than colored coats. This means more frequent bathing or using stronger
detergents, with added conditioning and care in attempting to remove
stains and discoloration. White hair is somewhat more fragile than
colored hair and can be easily damaged or broken. Damaged hair will
tangle more easily. Using heat can help remove dirt and stains, but heat
itself can cause hair to lose elasticity and break. Maintaining optimum
whiteness in pet coats requires finding the balance between cleaning and
overworking the coat. It is also important to recognize that white dogs
often have sensitive skin or allergy problems, and can have
post-grooming irritation from the harsher detergents or allergic
reaction to the colorants.
Copyright 2006, Barbara Bird aka BBird, Birdzeye Press,
Tucson, AZ. All copyright applies.
For permission to use or reprint ANY part or whole of
this article, please contact the author
by email at
petpals@dakotacom.net or
phone (520)795-5743.
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